Nano-BF3.SiO2: A reusable and eco-friendly catalyst for thioacetalization and trans-thioacetalization reactions

Authors

  • Abdolhamid Bamoniri Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, I. R Iran.
  • Ali Akbari Department of Chemistry, College of Science, Yazd University, Yazd. P.O.Box 89195-741, Iran.
Abstract:

Nano-silica supported boron trifluoride (BF3.SiO2) is an efficient, reusable and eco-friendly catalyst for chemoselective thioacetalization of aldehydes and ketones. So, this catalyst was applied for transthioacetalization of acetals and acylals into their corresponding 1,3-dithiolanes or 1,3-dithianes  in good to excellent yields. The reactions were carried out at room temperature under solvent free and grinding conditions in 1.5-2.5 minutes.

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Journal title

volume 1  issue 2

pages  87- 92

publication date 2011-12-01

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